Inhibition effect of carbon dioxide on the oxidation of hydrogen over a platinum foil catalyst

This paper investigates the catalytic ignition of the H₂/O₂/CO₂ mixture on platinum in a stagnation flow at atmospheric pressure experimentally and numerically. We measure the ignition temperatures of the gas mixtures flowing towards resistively heated platinum with various composition ratios and various diluent gases of N₂, Ar and CO₂. Compared with N₂ or Ar, the CO₂ dilution shows higher ignition temperature by about 50 K, even at the same composition ratio. The ignition temperature increase is proportional to the dilution ratio. Through the numerical simulation, it is illustrated that higher ignition temperature is caused by the adsorption of CO₂ and following dissociation on platinum surface, which was to date considered negligible in catalytic combustion.     

Current IMT-2000 R&D status and views in Korea

In this article Korean development of IMT-2000 is considered. It includes the second-generation digital mobile communications, R&D and standardization activities related to IMT-2000, and the authors' perspectives on IMT-2000 in Korea. In Korea, there are many activities for development of IMT-2000 radio transmission technologies, and the results of these activities will be the submission of technologies to the ITU. However, the Korean telecommunications standardization body (TTA) will make every effort to make a common global standard for IMT-2000. Therefore, the TTA will make a domestic standard for IMT-2000 after the ITU finalizes the related Recommendations. It seems to the authors that difficulties in harmonization in the TTA are very similar to difficulties in harmonization worldwide. The only way of reaching the harmonization of IMT-2000 in Korea is that the key players should have the view from the end users' seat     

An expectation-driven response understanding paradigm

This paper describes a model that can account for ad hoc user-responses to argument interrogative type of system-initiated questions. Successful implementation of the model can provide an alternative solution that is more effective than the menu-driven approach that has been proposed as a meager solution to enable the system to ask a question to the user. The proposed model assumes that when the system asks a question, it maintains an expectation of the potential answers. The system then uses the expectation as the focus to perform the most likely interpretation of the user's response. Without using such a focus the interpretation process could be unbounded. The interpretation process is mapped into a heuristic search problem. The interpretation process results in identifying a particular expectation-response relationship type, which the system can use to tailor its response strategy with respect to the given user-response. A prototype has been constructed to demonstrate the soundness of the proposed model     

Biochemical identification of transmembrane segments of the Ca(2+)-ATPase of sarcoplasmic reticulum

The transmembrane segments of sarcoplasmic reticulum Ca(2+)-ATPase were determined by trypsinization of cytoplasmic side-out intact sarcoplasmic reticulum vesicles. The membrane portion of tryptic digest comprising the transmembrane fragments, joined by the intravesicular segments, was separated by sodium dodecyl sulfate-polyacrylamide gel electrophoresis after labeling with fluorescein 5-maleimide in the presence of sodium dodecyl sulfate. In this way, seven fluorescent bands of tryptic fragments below 11 kDa were observed which were derived from 4 pairs of membrane spanning segments and one hydrophobic sequence at the C-terminal end. Two peptides of 10.8 and 10.6 kDa had the identical N-terminal sequence beginning at Glu826, representing the transmembrane segments M7 and M8 and their connecting loop. A band at 8.1 kDa contained one peptide beginning at Tyr36 (M1/loop/M2). A 7.7-kDa peptide starting at Leu253 (M3/loop/M4) and a 7.3-kDa peptide beginning at Ala752 (M5/loop/M6) were also observed. A band at 6.7 kDa contained two peptides, one beginning at Ser48 (M1/loop/M2) and another beginning at Tyr763 (M5/loop/M6). In addition, a 4-kDa peptide beginning at Met925 was observed. The size of this peptide did not allow for a complete pair of transmembrane segments, but this peptide could have been derived from trypsinolysis between the last pair of membrane spanning segments. These data therefore provide biochemical evidence for at least 8 transmembrane segments and perhaps two more at the C-terminal end of the enzyme.     

Novel T-rail electrodes for substrate removed low-voltage high-speed GaAs/AlGaAs electrooptic modulators

A novel traveling-wave electrode utilizing capacitively loaded T-rail elements was developed for low-voltage high-speed substrate-removed GaAs/AlGaAs electrooptic modulators. Electrodes with varying dimensions were fabricated and characterized. Electrode phase velocity, characteristic impedance, loss coefficient, and capacitive loading were extracted from the measured s-parameters up to 40 GHz. Electrode was also simulated using a finite-element solver. The measured and calculated electrode capacitance values were found to be in excellent agreement, showing that the electrode can be precisely designed. Approaches were outlined to provide a group velocity-matched very high-speed modulator electrode suitable for a low drive-voltage substrate-removed GaAs/AlGaAs electro-optic modulator     

Holographic polymer‐dispersed liquid crystal fabrication under electric field

The transmission mode of holographic polymer‐dispersed liquid crystals (HPDLCs) was developed an under electric field. It is reported that orientation of LC molecules under an electric field induces orientation of oligomer molecules giving rise to low off‐state diffraction and small grating shrinkage. Copyright © 2005 Society of Chemical Industry     

Properties of nanoporous organosilicate hybrid thin films with a bimodal pore size distribution

Low dielectric poly[methylsilsesquioxane‐ran‐trifluoropropylsilsesquioxane‐ran‐(2,4,6,8‐tetramethyl‐2,4,6,8‐tetraethylenecyclotetrasiloxane)silsesquioxane]s {P[M‐ran‐TFP‐ran‐(TCS)]SSQs} having various compositions were synthesized using trifluoropropyl trimethoxysilane, methyl trimethoxysilane and 2,4,6,8‐tetramethyl‐2,4,6,8‐tetra(trimethoxysilylethyl)cyclotetrasiloxane. The chemical composition of the polymers and the content of SiOH end‐groups were controlled by adjusting the reaction conditions, and they were characterized by ¹H‐NMR. The thermally decomposable trifluoropropyl groups on the P[M‐ran‐TFP‐ran‐(TCS)]SSQ backbone and heptakis(2,3,6‐tri‐O‐methyl)‐β‐cyclodextrin (CD) were employed as pore generators. The dielectric constants of the porous CD/P[M‐ran‐TFP‐ran‐(TCS)]SSQ films were in the range 2.0–2.7 (at 100 kHz) depending on the concentration of the porogens, and showed no change over 4 days under aqueous conditions. The pore size of the films showed a bimodal distribution, with diameters of ca 0.5–1.0 nm for those originating from the trifluoropropyl groups and 1.7 nm from the CD. The elastic modulus and hardness of the 30 vol% CD‐blended film with a dielectric constant of 2.26 were 2.40 and 0.38 GPa, respectively, as determined by a nanoindenter. Copyright © 2005 Society of Chemical Industry     

Optimal tradeoffs for location-based routing in large-scale ad hoc networks

Existing location-based routing protocols are not versatile enough for a large-scale ad hoc environment to simultaneously meet all of the requirements of scalability, bandwidth efficiency, energy efficiency, and quality-of-service routing. To remedy this deficiency, we propose an optimal tradeoff approach that: 1) constructs a hybrid routing protocol by combining well-known location-update schemes (i.e., proactive location updates within nodes' local regions and a distributed location service), and 2) derives its optimal configuration, in terms of location-update thresholds (both distance and time-based), to minimize the overall routing overhead. We also build a route-discovery scheme based on an Internet-like architecture, i.e., first querying the location of a destination, then applying a series of local-region routing until finding a complete route by aggregating the thus-found partial routes. To find the optimal thresholds for the hybrid protocol, we derive the costs associated with both location updates and route discovery as a function of location-update thresholds, assuming a random mobility model and a general distribution for route request arrivals. The problem of minimizing the total cost is then cast into a distributed optimization problem. We first prove that the total cost is a convex function of the thresholds, and then derive the optimal thresholds. Finally, we show, via simulation, that our analysis results indeed capture the real behavior.     

The microstructures of laser-alloyed Ni-Ta surface layers

Evaporated thin tantalum films on single and polycrystalline nickel have been laser surface alloyed using either continuous-wave CO₂ or Q-switched Nd-YAG radiation. In the case of the continuous-wave laser, surface alloys contain amorphous tantalum-rich regions, intermediate polycrystalline bands of TaNi, and an underlying Ni(Ta) solid solution. In the Q-switched laser case, a much more laterally uniform amorphous phase with approximately equal atomic fractions of nickel and tantalum is found, with little evidence of polycrystalline intermetallics.In situ annealing with the electron beam of the microscope results in formation of microcrystallites, predominantly nickel.